Category:OSWdaba9367be1f58149427010d501c9d7e: Difference between revisions

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Latest revision as of 06:04, 1 March 2025

ElectrochemicalImpedanceSpectroscopy
ID	OSWdaba9367be1f58149427010d501c9d7e
UUID	daba9367-be1f-5814-9427-010d501c9d7e
Label	ElectrochemicalImpedanceSpectroscopy
Machine compatible name	ElectrochemicalImpedanceSpectroscopy
Statements (outgoing)

Statements (incoming)

Description

Electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential. Impedimetric sensors are based on measurement of a concentration-dependent parameter taken from analysis of the respective electrochemical impedance spectra, or from the impedance magnitudes at a chosen fixed frequency. The sinusoidal current response lags behind the sinusoidal voltage perturbation by a phase angle φ. Resistances (e.g. to charge transfer) give a response in phase with the voltage perturbation; capacitances (e.g. double layer) give a response 90° out of phase; combinations of resistances and capacitances give phase angles between 0 and 90°. Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested are called complex plane (or Nyquist) plots. Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency are called Bode diagrams. Complex plane plots are the more commonly used for electrochemical sensors.

Category (Class)

OWL Class
Imported fromA prefixed IRI defining this entry as a imported term. In OSW the prefix must be a registered imported ontology.<br>Definition: OWL Class	https://w3id.org/emmo/domain/characterisation-methodology/chameo#ElectrochemicalImpedanceSpectroscopy

EmmoClass
Supercategories<br>Definition: Category (Class), OWL Class, EmmoClass	Impedimetry
Alternative label<br>Definition: EmmoClass	EIS [en]
metaclass<br>Definition: Category (Class), EmmoClass	EmmoClass

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jsondata

rdf_type

"owl:Class"

uuid

"daba9367-be1f-5814-9427-010d501c9d7e"

iri

"https://w3id.org/emmo/domain/characterisation-methodology/chameo#ElectrochemicalImpedanceSpectroscopy"

name

"ElectrochemicalImpedanceSpectroscopy"

label

text	"ElectrochemicalImpedanceSpectroscopy"
lang	"en"

description

text

"Electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential. Impedimetric sensors are based on measurement of a concentration-dependent parameter taken from analysis of the respective electrochemical impedance spectra, or from the impedance magnitudes at a chosen fixed frequency. The sinusoidal current response lags behind the sinusoidal voltage perturbation by a phase angle φ. Resistances (e.g. to charge transfer) give a response in phase with the voltage perturbation; capacitances (e.g. double layer) give a response 90° out of phase; combinations of resistances and capacitances give phase angles between 0 and 90°. Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested are called complex plane (or Nyquist) plots. Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency are called Bode diagrams. Complex plane plots are the more commonly used for electrochemical sensors."

lang

"en"