Property:Text
"Text" is a predefined property that represents text of arbitrary length and is provided by Semantic MediaWiki. This property is pre-deployed (also known as special property) and comes with additional administrative privileges but can be used just like any other user-defined property.
E
a system comprising one electrode in contact with an ionic conductor. +
electrochemicalhalfcell +
restrictions +
ElectrochemicalImmunity +
electrochemicalimmunity +
situation in which a material in a given environment undergoes negligible electrochemical corrosion. +
Electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential. Impedimetric sensors are based on measurement of a concentration-dependent parameter taken from analysis of the respective electrochemical impedance spectra, or from the impedance magnitudes at a chosen fixed frequency. The sinusoidal current response lags behind the sinusoidal voltage perturbation by a phase angle φ. Resistances (e.g. to charge transfer) give a response in phase with the voltage perturbation; capacitances (e.g. double layer) give a response 90° out of phase; combinations of resistances and capacitances give phase angles between 0 and 90°. Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested are called complex plane (or Nyquist) plots. Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency are called Bode diagrams. Complex plane plots are the more commonly used for electrochemical sensors. +
ElectrochemicalImpedanceSpectroscopy +
electrochemicalimpedancespectroscopy +
ElectrochemicalImpedanceSpectroscopyData +
a dataset resulting from an electrochemical impedance spectroscopy experiment or simulation +
electrochemicalimpedancespectroscopydata +
ElectrochemicalInterface +
electrochemicalinterface +
the two-dimensional space comprising the boundary between two electrochemical constituents +